Take a block of wax and drop it into molten wax. It sinks. Take a lump of metal and drop it
into the same metal, melted. It sinks. This is what solids do: cooling packs the particles
closer, so the solid weighs more for its size than the liquid it came from.
Now do it with water.
The ice floats — and that is the wrong way round. Almost everything else sinks in its own
liquid, and the reason water does not comes down to the shape of one molecule. Its two
hydrogens do not come off opposite each other; they come off the same side, about a hundred
and four degrees apart. The molecule is bent, and lopsided, and slightly sticky at both ends
— but only in particular directions.
Freeze it, and each molecule ends up holding exactly four neighbours. It cannot hold four at
those angles and stay close to all of them. To give every bond the direction it wants, it has
to hold its neighbours at arm's length. The crowd stops being a crowd and becomes a cage,
with nothing in the middle of it. Same water. About nine percent more room.
Nine percent does not sound like much until it has nowhere to go: a sealed bottle in a
freezer does not bulge, it splits, and water freezing in a crack takes mountains apart one
winter at a time.
Water is not even the only one — silicon, germanium, gallium, bismuth and antimony all do it.
And there is one more thing. Water is densest at about four degrees, not at zero, so a
cooling lake turns over and over until all of it reaches four — and then stops. The coldest
water is now the lightest, so it stays at the top, and that is where it freezes.
The ice forms a lid instead of a filling. The water underneath stays liquid all winter.
None of it is for anything. It is geometry — two bonds, a hundred and four degrees apart —
and everything after that is consequence.
00:00 The wrong way round
00:40 Why solids sink
01:34 What water does instead
02:30 The cage
04:03 Nine percent
04:48 Water is not special
05:19 The lake
06:24 The turn
Subtitles: English