The only reason Muzan is Scared of Tanjiro is be of his "Hanafuda Earrings" that Tanjiro posses, it reminded Muzan of his near death encounter Yoriichiri.
To avoid spoilers dont read this... this is just to avoid misinformation:
Yoriichi the guy that is shown is not related to tanjiro, yoriichi is just the friend of tanjiro's ancestor and taught sun breathing to the kamado house which is sun breating but ya know kamado.
Muzan Kibutsuji afraid of Tanjiro because he saw the earings, knowing that Tanjiro is the successor of Kamado family and possess a powerful ability that might kill him someday. Also Muzan knows that Tanjiro is much powerful than him once he became a demon.
Hah the title should be changed to tanjiro removing the sash demons head. Muzan isn't scared of tanjiro. He's scared because that hanafunda earrings reminds him of his near death encounter with yoriichi
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